Phase equilibria of Sn-Sb-Cu system

被引：37

作者：

Chen, Sinn-wen ^{[1
]}

Zi, An-ren ^{[1
]}

Gierlotka, Wojciech ^{[2
]}

Yang, Ching-feng ^{[1
]}

Wang, Chao-hong ^{[3
]}

Lin, Shih-kang ^{[1
,4
]}

Hsu, Chia-ming ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu, Taiwan

[2] Yuan Ze Univ, Dept Chem Engn & Mat Sci, Chungli, Taiwan

[3] Natl Chung Cheng Univ, Dept Chem Engn, Chiayi, Taiwan

[4] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 70101, Taiwan

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2012年 / 132卷 / 2-3期

关键词：

Alloys; Phase equilibria; Thermodynamic properties; Computer modeling and simulation; INTERFACIAL REACTIONS; SOLDERS; DIAGRAM; ALLOYS; SUBSTRATE; DATABASE; EMF;

D O I：

10.1016/j.matchemphys.2011.11.088

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Ternary Sn-Sb-Cu alloys are prepared. The primary solidification phases, the phase transformation temperatures, and the equilibrium phases at 250 degrees C are experimentally determined. The liquidus projection and the 250 degrees C phase equilibria isothermal section of the Sn-Sb-Cu system are proposed based on the experimental results and the phase diagrams of the three constituent binary systems. Using the CALPHAD approach, thermodynamic modeling of the Sn-Sb-Cu ternary system is carried out based on the experimental information determined in this study and those in the literatures, together with the developed thermodynamic models of the three constituent binary systems. The liquidus projection and the isothermal sections are then calculated using the models developed in this study and the results are in good agreement with experimental determinations. (c) 2011 Elsevier B.V. All rights reserved.

引用

页码：703 / 715

页数：13

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