Solubility of C60 fullerene

被引：132

作者：

Marcus, Y ^{[1
]}

Smith, AL

Korobov, MV

Mirakyan, AL

Avramenko, NV

Stukalin, EB

机构：

[1] Hebrew Univ Jerusalem, Dept Inorgan & Analyt Chem, IL-91904 Jerusalem, Israel

[2] Drexel Univ, Dept Chem, Philadelphia, PA 19104 USA

[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2001年 / 105卷 / 13期

关键词：

D O I：

10.1021/jp0023720

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The most recent and comprehensive set of solubility data of C-60 fullerene in various solvents at 298 and 303 K was treated by multivariate stepwise linear regression applied as the linear solvation energy approach. In a few cases where the fullerene formed crystalline solvates, the enthalpy of incongruent melting and the temperature of maximum solubility were used to determine the "hypothetical solubility" of the unsolvated C-60, which was then used in the statistical procedure instead of the solubility of the solvate. The "ideal" solubility of the fullerene was estimated, and the "nonideal" part of the Gibbs energy of solution was then related to solute-solvent interactions. Increasing molar volume and solvent polarity las measured by the Dimroth-Reichardt "general polarity" parameter, E-T(30)) diminished the solubility of C-60, whereas electron pair donation ability and polarizability enhanced solubility.

引用

页码：2499 / 2506

页数：8

共 50 条

[21] Reactivity of fullerene C60
A. F. Shestakov
Russian Journal of General Chemistry, 2008, 78 : 811 - 821
[22] SUMANENE AND FULLERENE C60
Melker, Alexander, I
Krupina, Maria A.
Zarafutdinov, Ruslan M.
MATERIALS PHYSICS AND MECHANICS, 2019, 41 (01): : 45 - 51
[23] Using Hansen solubility parameters to correlate solubility of C60 fullerene in organic solvents and in polymers
Hansen, CM
Smith, AL
CARBON, 2004, 42 (8-9) : 1591 - 1597
[24] The Chemistry of Fullerene C60
Chim Ind, 9 (1085):
[25] CORAL: QSPR models for solubility of [C60] and [C70] fullerene derivatives
Toropova, Alla P.
Toropov, Andrey A.
Benfenati, Emilio
Gini, Giuseppina
Leszczynska, Danuta
Leszczynski, Jerzy
MOLECULAR DIVERSITY, 2011, 15 (01) : 249 - 256
[26] Synthesis and solubility properties of C60 fullerene derivatives bearing carboxy groups
Tomioka, H.
Yamamoto, K.
Jornal of the Chemical Society. Perkin Transactions 1,
[27] Effect of fullerene C60 on thermal degradation of fullerene-containing polymers and blends of polymers with fullerene C60
Shibaev, LA
Antonova, IA
Vinogradova, LV
Ginzburg, BM
Zgonnik, VN
Melenevskaya, EY
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 1998, 71 (05) : 862 - 868
[28] Is the C60 fullerene molecule toxic?!
Andrievsky, G
Klochkov, V
Derevyanchenko, L
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2005, 13 (04) : 363 - 376
[29] Molecular recognition of fullerene C60
Raston, CL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U926 - U926
[30] C60 fullerene binding to DNA
Mansoor H. Alshehri
Barry J. Cox
James M. Hill
The European Physical Journal B, 2014, 87

← 1 2 3 4 5 →