Enabling Catalytic Oxidation of Li2O2 at the Liquid-Solid Interface: The Evolution of an Aprotic Li-O2 Battery

被引：120

作者：

Feng, Ningning ^{[1
]}

He, Ping ^{[1
]}

Zhou, Haoshen ^{[1
,2
]}

机构：

[1] Nanjing Univ, Natl Lab Solid State Microstruct, Coll Engn & Appl Sci, Nanjing 210093, Jiangsu, Peoples R China

[2] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, Japan

来源：

CHEMSUSCHEM | 2015年 / 8卷 / 04期

基金：

中国国家自然科学基金;

关键词：

charging potential; energy storage; homogeneous catalysis; Li-O-2; batteries; redox mediators; BIFUNCTIONAL CATALYST; OXYGEN; PERFORMANCE; COMPOSITE; ELECTRODE;

D O I：

10.1002/cssc.201403338

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We show that by using a suitable soluble redox mediator, the charging overpotential can be reduced and the round-trip efficiency can be improved in an aprotic Li-O-2 battery. Not only do we explore a new redox couple, 10-methyl-10H-phenothiazine, as a soluble catalyst that improves the electrochemical performance, but we also propose possible challenges that need to be overcome for the future improvement of aprotic Li-O-2 batteries.

引用

页码：600 / 602

页数：3

共 50 条

[41] Mechanistic insights for the development of Li-O2 battery materials: addressing Li2O2 conductivity limitations and electrolyte and cathode instabilities
McCloskey, Bryan D.
Burke, Colin M.
Nichols, Jessica E.
Renfrew, Sara E.
CHEMICAL COMMUNICATIONS, 2015, 51 (64) : 12701 - 12715
[42] Impact of Li2O2 Particle Size on Li-O2 Battery Charge Process: Insights from a Multiscale Modeling Perspective
Yin, Yinghui
Gaya, Caroline
Torayev, Amangeldi
Thangavel, Vigneshwaran
Franco, Alejandro A.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2016, 7 (19): : 3897 - 3902
[43] Achieving Low Overpotential Li-O2 Battery Operations by Li2O2 Decomposition through One-Electron Processes
Xie, Jin
Dong, Qi
Madden, Ian
Yao, Xiahui
Cheng, Qingmei
Dornath, Paul
Fan, Wei
Wang, Dunwei
NANO LETTERS, 2015, 15 (12) : 8371 - 8376
[44] Clean Electrocatalysis in a Li2O2 Redox-Based Li-O2 Battery Built with a Hydrate-Melt Electrolyte
Wu, Shichao
Qiao, Yu
Yang, Sixie
Tang, Jing
He, Ping
Zhou, Haoshen
ACS CATALYSIS, 2018, 8 (02): : 1082 - 1089
[45] The Decisive Role of Li2O2 Desorption for Oxygen Reduction Reaction in Li-O2 Batteries
Xu, Chengyang
Ge, Aimin
Kannari, Koki
Peng, Baoxu
Xue, Min
Ding, Bing
Inoue, Ken-ichi
Zhang, Xiaogang
Ye, Shen
ACS ENERGY LETTERS, 2023, 8 (03) : 1289 - 1299
[46] Lithium and oxygen vacancies and their role in Li2O2 charge transport in Li-O2 batteries
Varley, J. B.
Viswanathan, V.
Norskov, J. K.
Luntz, A. C.
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (02) : 720 - 727
[47] Enhanced Li2O2 Decomposition in Rechargeable Li-O2 Battery by Incorporating WO3 Nanowire Array Photocatalyst
Feng, Yaya
Xue, Hairong
Wang, Tao
Gong, Hao
Gao, Bin
Xia, Wei
Jiang, Cheng
Li, Jingjing
Huang, Xianli
He, Jianping
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (06): : 5931 - 5939
[48] Photoactive cobalt-bipyridine electron mediator promotes reversible Li2O2 formation in irradiated Li-O2 battery
Li, Xinjian
Su, Yanhui
Ma, Yong
Wei, Le
He, Ying
Gu, Yuting
Mei, Shiwei
Mu, Qiaoqiao
Peng, Chengyuan
Peng, Yang
Deng, Zhao
APPLIED CATALYSIS B-ENVIRONMENTAL, 2023, 337
[49] Evidence of catalyzed oxidation of Li2O2 for rechargeable Li-air battery applications
Harding, Jonathon R.
Lu, Yi-Chun
Tsukada, Yasuhiro
Shao-Horn, Yang
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (30) : 10540 - 10546
[50] The influence of transition metal oxides on the kinetics of Li2O2 oxidation in Li-O2 batteries: high activity of chromium oxides
Yao, Koffi P. C.
Lu, Yi-Chun
Amanchukwu, Chibueze V.
Kwabi, David G.
Risch, Marcel
Zhou, Jigang
Grimaud, Alexis
Hammond, Paula T.
Barde, Fanny
Shao-Horn, Yang
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (06) : 2297 - 2304

← 1 2 3 4 5 →