Enabling Catalytic Oxidation of Li2O2 at the Liquid-Solid Interface: The Evolution of an Aprotic Li-O2 Battery

被引：120

作者：

Feng, Ningning ^{[1
]}

He, Ping ^{[1
]}

Zhou, Haoshen ^{[1
,2
]}

机构：

[1] Nanjing Univ, Natl Lab Solid State Microstruct, Coll Engn & Appl Sci, Nanjing 210093, Jiangsu, Peoples R China

[2] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, Japan

来源：

CHEMSUSCHEM | 2015年 / 8卷 / 04期

基金：

中国国家自然科学基金;

关键词：

charging potential; energy storage; homogeneous catalysis; Li-O-2; batteries; redox mediators; BIFUNCTIONAL CATALYST; OXYGEN; PERFORMANCE; COMPOSITE; ELECTRODE;

D O I：

10.1002/cssc.201403338

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We show that by using a suitable soluble redox mediator, the charging overpotential can be reduced and the round-trip efficiency can be improved in an aprotic Li-O-2 battery. Not only do we explore a new redox couple, 10-methyl-10H-phenothiazine, as a soluble catalyst that improves the electrochemical performance, but we also propose possible challenges that need to be overcome for the future improvement of aprotic Li-O-2 batteries.

引用

页码：600 / 602

页数：3

共 50 条

[1] Li2O2 oxidation: the charging reaction in the aprotic Li-O2 batteries
Cui, Qinghua
Zhang, Yelong
Ma, Shunchao
Peng, Zhangquan
SCIENCE BULLETIN, 2015, 60 (14) : 1227 - 1234
[2] Li2O2 oxidation: the charging reaction in the aprotic Li-O2 batteries
Qinghua Cui
Yelong Zhang
Shunchao Ma
Zhangquan Peng
ScienceBulletin, 2015, 60 (14) : 1227 - 1234
[3] Homogeneous nucleation of Li2O2 under Li-O2 battery discharge
Zakharchenko, Tatiana K.
Sergeev, Artem V.
D. Bashkirov, Alexander
Neklyudova, Polina
Cervellino, Antonio
Itkis, Daniil M.
Yashina, Lada V.
NANOSCALE, 2020, 12 (07) : 4591 - 4601
[4] Pt and Pd catalyzed oxidation of Li2O2 and DMSO during Li-O2 battery charging
Gittleson, Forrest S.
Ryu, Won-Hee
Schwab, Mark
Tong, Xiao
Taylor, Andre D.
CHEMICAL COMMUNICATIONS, 2016, 52 (39) : 6605 - 6608
[5] A highly efficient Li2O2 oxidation system in Li-O2 batteries
Hase, Yoko
Seki, Juntaro
Shiga, Tohru
Mizuno, Fuminori
Nishikoori, Hidetaka
Iba, Hideki
Takechi, Kensuke
CHEMICAL COMMUNICATIONS, 2016, 52 (82) : 12151 - 12154
[6] A Synergistic Catalytic Mechanism for Oxygen Evolution Reaction in Aprotic Li-O2 Battery
Cai, Senrong
Zheng, Mingsen
Lin, Xiaodong
Lei, Ming
Yuan, Ruming
Dong, Quanfeng
ACS CATALYSIS, 2018, 8 (09): : 7983 - 7990
[7] The Influence of Water and Protons on Li2O2 Crystal Growth in Aprotic Li-O2 Cells
Schwenke, K. Uta
Metzger, Michael
Restle, Tassilo
Piana, Michele
Gasteiger, Hubert A.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (04) : A573 - A584
[8] Solid-state activation of Li2O2 oxidation kinetics and implications for Li-O2 batteries
Yao, Koffi P. C.
Risch, Marcel
Sayed, Sayed Youssef
Lee, Yueh-Lin
Harding, Jonathon R.
Grimaud, Alexis
Pour, Nir
Xu, Zhichuan
Zhou, Jigang
Mansour, Azzam
Barde, Fanny
Shao-Horn, Yang
ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (08) : 2417 - 2426
[9] Li-O2 Battery Degradation by Lithium Peroxide (Li2O2): A Model Study
Younesi, Reza
Hahlin, Maria
Bjorefors, Fredrik
Johansson, Patrik
Edstrom, Kristina
CHEMISTRY OF MATERIALS, 2013, 25 (01) : 77 - 84
[10] Nature of Li2O2 Oxidation in a Li-O2 Battery Revealed by Operando X-ray Diffraction
Ganapathy, Swapna
Adams, Brian D.
Stenou, Georgiana
Anastasaki, Maria S.
Goubitz, Kees
Miao, Xue-Fei
Nazar, Linda F.
Wagemaker, Marnix
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (46) : 16335 - 16344

← 1 2 3 4 5 →