First neutral dinuclear cobalt complex formed by bridging [μ-O2P(H)R]- ligands: synthesis, X-ray crystal structure and quantum-chemical study

被引：7
|
作者：
Yakhvarov, Dmitry G. [1 ,2 ]
Trofimova, Ekaterina A. [1 ]
Dobrynin, Alexey B. [1 ]
Gerasimova, Tatiana P. [1 ]
Katsyuba, Sergey A. [1 ]
Sinyashin, Oleg G. [1 ]
机构：
[1] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia
[2] Kazan Fed Univ, AM Butlerov Inst Chem, Kazan 420008, Russia
来源：
MENDELEEV COMMUNICATIONS | 2015年 / 25卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; DESIGN; MOFS; SEPARATION; METHANE;
D O I：
10.1016/j.mencom.2015.01.009
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of cobalt dibromide hexahydrate with 2,2'-bipyridine (bpy) and 9-anthrylphosphinic acid AntP(O)(OH)H (Ant = 9-anthryl) leads to the first example of a neutral dinuclear cobalt(II) complex {Co2Br2[mu-O2P(H)Ant](2)(bpy)(2)} formed by two bridging [mu-O2P(H)Ant](-) ligands. The complex has been characterized by X-ray diffraction analysis and quantum-chemical calculations.
引用
收藏
页码：27 / 28
页数：2
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