Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[μ-O2P(H)Mes]2(bpy)4}Br2

被引：6
|
作者：
Trofimova, Ekaterina A. [1 ]
Dobrynin, Alexey B. [1 ]
Gerasimova, Tatiana P. [1 ]
Katsyuba, Sergey A. [1 ]
Sinyashina, Oleg G. [1 ]
Yakhvarov, Dmitry G. [1 ,2 ]
机构：
[1] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia
[2] Kazan Volga Reg Fed Univ, AM Butlerov Inst Chem, Kazan 420008, Russia
来源：
MENDELEEV COMMUNICATIONS | 2013年 / 23卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
METAL-ORGANIC FRAMEWORKS; COORDINATION NETWORKS; DESIGN; STATE;
D O I：
10.1016/j.mencom.2013.05.004
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of cobalt dibromide hexahydrate with 2,2'-bipyridine (bpy) and mesitylphosphinic acid MesP(O)(OH)H (Mes = = 2,4,6-trimethylphenyl) under solvothermal synthesis conditions leads to a new dinuclear cobalt(n) complex {Co-2[mu-O2P(H)Mes](2)(bpy)(4)]Br-2 formed by two bridging [mu-O2P(H)Mes}(-) ligands. X-ray crystal structure analysis of the complex displayed that cobalt ions have distorted octahedral coordination and are doubly bridged by two mesitylphosphinato ligands.
引用
收藏
页码：135 / 136
页数：2
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