Ferrocene Macrocyclic Schiff Base Complex: Synthesis, Structure and Recognition Properties for Dual Hg2+ and Cu2+

被引：6
|
作者：
Liu, Xiaoju [1 ]
Xiang, Yulin [1 ]
Ma, Xiangrong [1 ]
Ren, Guoyu [1 ]
Gao, Liguo [1 ]
机构：
[1] Yu Lin Univ Yulin, Inst Chem Engn, Key Lab Synthet & Nat Chem, Minist Educ, Chongwen Ave 4, Yulin 719000, Shaanxi, Peoples R China
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2017年 / 87卷 / 12期
关键词：
ferrocene; ion recognition; fluorescence sensor; Hg2+ and Cu2+ cation sensing; ANIONS; MOLECULES; RECEPTORS;
D O I：
10.1134/S1070363217120428
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A probe based on ferrocene structure has been designed, synthesized and elucidated from the single crystal X-ray method. It demonstrated fluorescence response to Hg2+ and Cu2+ in CH3OH. The results indicated that the title complex could be applied in the multianalyte detection. Binding ability of receptor 3 in CH3OH was tested for various cations (Fe3+, Co2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+, and Ba2+ in water). The computed binding constants for Hg2+ and Cu2+ indicated a distinct absorbance shift. The receptor is an attractive array due to its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in biology, environmental sciences and material chemistry.
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页码：2986 / 2988
页数：3
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