Characterization of activated biomass carbon from tea leaf for supercapacitor applications

被引:54
|
作者
Thirumal, V [1 ]
Yuvakkumar, R. [1 ]
Ravi, G. [1 ]
Dineshkumar, G. [2 ]
Ganesan, M. [2 ]
Alotaibi, Saad H. [3 ]
Velauthapillai, Dhayalan [4 ]
机构
[1] Alagappa Univ, Dept Phys, Karaikkudi 630003, Tamil Nadu, India
[2] CSIR Cent Electrochem Res Inst, Electrochem Power Sources Div, Karaikkudi 630003, Tamil Nadu, India
[3] Taif Univ, Turabah Univ Coll, Dept Chem, POB 11099, At Taif 21944, Saudi Arabia
[4] Western Norway Univ Appl Sci, Fac Engn & Sci, N-5063 Bergen, Norway
关键词
Tea waste; Biomass; Activated carbon; CVD; Supercapacitor; CHEMICAL ACTIVATION; PERFORMANCE; FABRICATION; ADSORPTION; FIBER;
D O I
10.1016/j.chemosphere.2021.132931
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this study, a facile synthesis of chemical and thermal activation of biomass tea-waste materials was explored. A tea-waste biosource carbon was explored by chemical vapor deposition (CVD) method at 700 degrees C. The KOHtreated carbon (AC-KH) and H3PO4-treated carbon (AC-HP) were systematically studied for morphological characteristics and showed good morphological structures and a few transparent focused layered nanosheets. The elemental analysis done by scanning electron microscopy with energy-dispersive X-ray spectroscopy confirmed the presence of activated carbon. Fourier transform infrared spectroscopy (FT-IR) showed carbon-containing functional groups. The electrochemical analysis showed cyclic voltammetry (CV) curves for electric double layer capacitance (EDLC) with 3 M KOH electrolyte. The Nyquist plot obtained using electrochemical impedance spectroscopy (EIS) showed charge transfer resistance value (R-ct) of 6.08 Omega. The electrochemical galvanostatic charge-discharge (GCD) study was conducted to obtain the specific capacitance (Scp) values of AC-KH, which were found to be 131.95 F/g at 0.5 A/g and also AC-HP active material was observed 55.76 F/g at 1 A/g. The ACKH showed superior electrochemical performance when compared to AC-HP material. Hence, AC-KH is a promising active material for high-energy supercapacitor applications.
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页数:8
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