The first separation and stereochemical determination of bis(α-hydroxyalkyl) phosphinic acids diastereoisomers

被引：26
|
作者：
Kaboudin, B [1 ]
Haghighat, H [1 ]
机构：
[1] IASBS, Dept Chem, Zanjan 451951159, Iran
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 46期
关键词：
phosphinic acids; stereochemistry; microwave; trimethyl orthoformate;
D O I：
10.1016/j.tetlet.2005.09.081
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A separation of bis(alpha-hydroxyalkyl) phosphinic acid diastereoisomers is described. A novel method for the determination stereochemistry of bis(alpha-hydroxyalkyl) phosphinic acid diastereoisomers has been developed. The stereochemistry of one diastereoisomer was confirmed after converting to the corresponding methyl ester using trimethyl orthoformate. (c) 2005 Published by Elsevier Ltd.
引用
收藏
页码：7955 / 7957
页数：3
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