Green Synthesis of Indeno[1,2-b]quinoxalines Using β-Cyclodextrin as Catalyst

被引：6
|
作者：
Liao, Li-Guo [1 ,2 ]
Song, Meng-Meng [3 ]
Feng, Jun-Feng
Tan, Min [1 ,2 ]
Liu, Fan [1 ,2 ]
Qiu, Zhen-Jiang [1 ,2 ]
Zhang, Sheng [3 ]
Li, Bang-Jing [1 ,2 ]
机构：
[1] Chinese Acad Sci, Chengdu Inst Biol, Key Lab Mt Ecol Restorat & Bioresource Utilizat, Chengdu 610041, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Sichuan Univ, Polymer Res Inst, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China
来源：
MOLECULES | 2022年 / 27卷 / 02期
关键词：
indeno[1,2-b]quinoxalines; beta-CD; environmentally friendly method; reusable catalyst; ATOM ECONOMY; DERIVATIVES; QUINOXALINES; KETONES; ACID;
D O I：
10.3390/molecules27020580
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
An efficient, mild, and green method was developed for the synthesis of indeno[1,2-b]quinoxaline derivatives via o-phenylenediamine (OPD) and 2-indanone derivatives utilizing beta-cyclodextrin (beta-CD) as the supramolecular catalyst. The reaction can be carried out in water and in a solid state at room temperature. beta-CD can also catalyze the reaction of indan-1,2-dione with OPD with a high degree of efficiency. Compared to the reported methods, this procedure is milder, simpler, and less toxic, making it an eco-friendly alternative. In addition, the beta-CD can be recovered and reused without the loss of activity.
引用
收藏
页数：12
相关论文
共 50 条
  • [41] Indeno[1,2-b]pyridin-4-yl-amine
    Gorlitzer, K
    Herbig, S
    Walter, RD
    PHARMAZIE, 1997, 52 (07): : 504 - 510
  • [42] Catalyst-free direct synthesis of indeno[1,2-b]indol-5(4bH)-yl benzimidamides
    Gomaa, Mohsen A. -M.
    Hassan, Doaa K.
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2023, 78 (05): : 261 - 265
  • [43] Synthesis and cytotoxicity studies of cyclohepta[b]indoles, benzo[6,7]cyclohepta[1,2-b]indoles, indeno[1,2-b]indoles, and benzo[a]carbazoles
    Hong, Bor-Cherng
    Jiang, Yea-Fen
    Chang, Yi-Ling
    Lee, Shiow-Ju
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2006, 53 (03) : 647 - 662
  • [44] A Simple and Efficient Synthesis of Highly Substituted Indeno[1,2-b]pyrrole and Acenaphtho[1,2-b]pyrrole Derivatives by Tandem Three-Component Reactions
    Tang, Xiaodong
    Zhu, Songlei
    Ma, Ying
    Wen, Ren
    Cen, Lanqi
    Gong, Panwei
    Wang, Jing
    MOLECULES, 2018, 23 (11):
  • [45] SYNTHESIS OF AZULENO[1,2-B]PYRROLE AND AZULENO[1,2-B]FURAN
    FUJIMORI, K
    FUKAZAWA, H
    NEZU, Y
    YAMANE, K
    YASUNAMI, M
    TAKASE, K
    CHEMISTRY LETTERS, 1986, (06) : 1021 - 1024
  • [46] ON THE REACTION OF N-VINYLIMINOPHOSPHORANES .16. A NEW SYNTHESIS OF 5H-INDENO[1,2-B]PYRIDINES AND 5H-INDENO[1,2-B]PYRIDIN-5-ONES
    NITTA, M
    OHNUMA, M
    LINO, Y
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (05): : 1115 - 1118
  • [47] Fabrication and characterization of inorganic-organic hybrid copper ferrite anchored on chitosan Schiff base as a reusable green catalyst for the synthesis of indeno[1,2-b]indolone derivatives
    Hassanpour, Hannaneh
    Naeimi, Hossein
    RSC ADVANCES, 2024, 14 (24) : 17296 - 17305
  • [48] SYNTHESIS OF SOME 11H-INDENO[1,2-B]QUINOXALIN-11-ONES
    DEADY, LW
    DESNEVES, J
    ROSS, AC
    TETRAHEDRON, 1993, 49 (43) : 9823 - 9828
  • [49] Synthesis and antitumor activity of some indeno[1,2-b]quinoline-based bis carboxamides
    Deady, LW
    Desneves, J
    Kaye, AJ
    Finlay, GJ
    Baguley, BC
    Denny, WA
    BIOORGANIC & MEDICINAL CHEMISTRY, 2000, 8 (05) : 977 - 984
  • [50] Synthesis and Characterization of New Indeno[1,2-b]fluorene6,12-dione Derivatives
    Wang Jing
    Wu Linli
    Wang Qian
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2023, 43 (01) : 223 - 228
12345