Green Synthesis of Indeno[1,2-b]quinoxalines Using β-Cyclodextrin as Catalyst

被引：6
|
作者：
Liao, Li-Guo [1 ,2 ]
Song, Meng-Meng [3 ]
Feng, Jun-Feng
Tan, Min [1 ,2 ]
Liu, Fan [1 ,2 ]
Qiu, Zhen-Jiang [1 ,2 ]
Zhang, Sheng [3 ]
Li, Bang-Jing [1 ,2 ]
机构：
[1] Chinese Acad Sci, Chengdu Inst Biol, Key Lab Mt Ecol Restorat & Bioresource Utilizat, Chengdu 610041, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Sichuan Univ, Polymer Res Inst, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China
来源：
MOLECULES | 2022年 / 27卷 / 02期
关键词：
indeno[1,2-b]quinoxalines; beta-CD; environmentally friendly method; reusable catalyst; ATOM ECONOMY; DERIVATIVES; QUINOXALINES; KETONES; ACID;
D O I：
10.3390/molecules27020580
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
An efficient, mild, and green method was developed for the synthesis of indeno[1,2-b]quinoxaline derivatives via o-phenylenediamine (OPD) and 2-indanone derivatives utilizing beta-cyclodextrin (beta-CD) as the supramolecular catalyst. The reaction can be carried out in water and in a solid state at room temperature. beta-CD can also catalyze the reaction of indan-1,2-dione with OPD with a high degree of efficiency. Compared to the reported methods, this procedure is milder, simpler, and less toxic, making it an eco-friendly alternative. In addition, the beta-CD can be recovered and reused without the loss of activity.
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页数：12
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