The aminophosphine-phosphinites and related ligands: synthesis, coordination chemistry and enantioselective catalysis

被引：92
|
作者：
Agbossou, F
Carpentier, JF
Hapiot, F
Suisse, I
Mortreux, A
机构：
[1] Ecole Natl Super Chim Lille, USTL, CNRS, Lab Catalyse Heterogene & Homogene, F-59652 Villeneuve Dascq, France
[2] Univ Artois, Lab Physicochim Interfaces & Applicat, CRUAL, Fac Sci J Perrin, F-62307 Lens, France
来源：
COORDINATION CHEMISTRY REVIEWS | 1998年 / 178卷
关键词：
aminophosphine-phosphinites; asymmetric catalysis; asymmetric C-C formation; asymmetric hydroformylation; asymmetric hydrogenation; asymmetric hydrosilylation; chiral diphosphines; cobalt; nickel; palladium; platinum; rhodium; ruthenium;
D O I：
10.1016/S0010-8545(98)00088-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and coordination chemistry of aminophosphine-phosphinites (AMPP) and closely related ligands is reviewed. Asymmetric catalytic reactions involving organometallic-AMPP complexes are presented. Examples of enantioselective C-C bond formation in the presence of nickel- (dienes and diene-olefins dimerization,, allylic substitution) and palladiumAMPP catalysts (nucleophilic addition to allylic substrates), hydroformylation based on platinum and rhodium complexes, rhodium-based hydrosilylation, hydrogenation of C double bond C and C double bond O bonds in the presence of rhodium and ruthenium complexes and home Diels-Alder catalyzed by cobalt species are presented. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：1615 / 1645
页数：31
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