Phase diagram of water in the vicinity of the triple point

被引：8

作者：

Tkachev, SN ^{[1
]}

Nasimov, RM ^{[1
]}

Kalinin, VA ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI, INST PHYS EARTH, MOSCOW 123810, RUSSIA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1996年 / 105卷 / 09期

关键词：

D O I：

10.1063/1.472191

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The melting curves of ice VI and ice VII were measured using a diamond-anvil pressure cell up to P=2.8 GPa and T=400 K and their metastable extensions. We found the existence of the metastable extension of the phase boundary between ice VI and liquid water within the stable region of ice VII and confirmed the presence of the metastable extension of the phase boundary between ice VII and liquid water within the stable field of ice VI. We found that the curvature of the ice VI-ice VII phase boundary is more pronounced than previously reported. The complete interpretation of our results might be made on the basis of thermodynamics of liquids in small confining systems. (C) 1996 American Institute of Physics.

引用

页码：3722 / 3725

页数：4

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