Catalytic Conversion of Biomass-Derived 1,2-Propanediol to Propylene Oxide over Supported Solid-Base Catalysts

被引：7
|
作者：
Liu, Chengyun [1 ]
Xin, Junna [1 ]
Tan, Jihuai [1 ]
Liu, Tuan [1 ]
Kessler, Michael R. [1 ,2 ]
Zhang, Jinwen [1 ]
机构：
[1] Washington State Univ, Composite Mat & Engn Ctr, Pullman, WA 99164 USA
[2] North Dakota State Univ, Dept Mech Engn, Fargo, ND 58108 USA
来源：
ACS OMEGA | 2018年 / 3卷 / 08期
关键词：
DEHYDRATION;
D O I：
10.1021/acsomega.8b01121
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of supported alkali metal salts,were, investigated as catalysts to produce propylene oxide (PO) from biomass-derived 1,2-propanediol via dehydrative epox-idation in a solid gas reaction system. The effects of supports, cations, and anions in the alkali metal salts and calcination temperature were investigated by X-ray diffraction, and CO2-temperature-programmed desorption. The results indicate the catalysts with relative mild basicity having higher yields of PO. The highest yield of PO is 58.2% from reactions at 400 degrees C at an atmospheric pressure over KNO3/SiO2. In addition, the catalyst could be reused after calcination in air at 550 degrees C.
引用
收藏
页码：8718 / 8723
页数：6
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