Relative β-elimination rates of heteroatoms from alkyl and aminyl radicals

被引：16
|
作者：
Kim, S [1 ]
Cheong, JH [1 ]
机构：
[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 10期
关键词：
D O I：
10.1039/a802507j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The relative beta-elimination rates of heteroatoms from alkyl radicals are in the order of Br greater than or equal to PhSe > PhS > PhSO2 > Cl, whereas the order of PhSe > PhSO2 > PhS similar to Br is observed for beta-eliminations from aminyl radicals, indicating a dependence on the nature of radicals.
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页码：1143 / 1144
页数：2
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