A new coordination compound formed between 1,4-bis(nitronyl nitroxide)benzene and copper(II)hexafluoroacetylacetonate

被引：13
|
作者：
Zhang, DQ [1 ]
Liu, W
Xu, W
Jin, XL
Zhu, DB
机构：
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Organ Solids, Beijing 100080, Peoples R China
[2] Peking Univ, Inst Chem Phys, Natl Struct Lab Stable & Unstable Species, Beijing 100871, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2001年 / 318卷 / 1-2期
基金：
中国国家自然科学基金;
关键词：
crystal structures; copper nitronyl nitroxide; magnetism;
D O I：
10.1016/S0020-1693(01)00386-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new coordination compound 1 derived from 1,4-bis(nitronyl nitroxide)benzene and copper(II)hexafluoroacetylacetonate [Cu(hfac)(2)] was prepared and characterized. It crystallizes in the monoclinic space group P2(1)/n with a = 13.134(3) Angstrom, b = 12.040(2) Angstrom, c = 17.520(4) Angstrom, beta = 104.02(3)degrees, V = 2688.0(10) Angstrom (3), Z = 2. Its magnetic property was investigated with ESR and SQUID and the magnetic data were qualitatively analyzed in combination with its crystal structure. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：84 / 88
页数：5
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