Chemical solution deposition of multiferroic La0.7Sr0.3MnO3, BaTiO3 thin films prepared by ink plotting

被引:7
|
作者
Kirchner, A. [1 ]
Arin, M. [2 ]
Lommens, P. [2 ]
Granados, X. [3 ]
Ricart, S. [3 ]
Holzapfel, B. [1 ]
Van Driessche, I. [2 ]
机构
[1] IFW Dresden, Inst Metall Mat, D-01069 Dresden, Germany
[2] Univ Ghent, SCRiPTs, Dept Inorgan & Phys Chem, B-9000 Ghent, Belgium
[3] CSIC ICMAB, Mat Sci Inst Barcelona, Bellaterra 08193, Spain
关键词
Aqueous solution; La0.7Sr0.3MnO3; BaTiO3; Multiferroics; Ink plotting; CEO2 BUFFER LAYERS; METAL; TEMPERATURE; TRANSITION; MAGNETISM; SRTIO3;
D O I
10.1016/j.jallcom.2011.11.025
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ferroelectric BaTiO3 (BTO) as well as ferromagnetic La0.7Sr0.3MnO3 (LSMO) thin films were prepared by chemical solution deposition (CSD). Based on these, a multiferroic architecture stack of La0.7Sr0.3MnO3/BaTiO3 layers was developed. Aqueous, environment friendly precursor solutions were formulated for both materials. These are used for ink plotting on SrTiO3 (100) substrates. Films were subjected to a subsequent thermal treatment at the corresponding crystallization temperature. The structural as well as the magnetic and electric properties are presented. The Curie temperature of the ferromagnetic LSMO layer with a film thickness of only 60 nm was determined to 360 K. The magnetization curve indicates a hysteresis loop with a saturation magnetization above 400 emu/cm(3). The ferroelectric character of the BTO films was demonstrated by polarization curves. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:16 / 19
页数:4
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