Hydroboration of the amino(imino)borane [Me3C(Me3Si)N]B[N(CMe3)]

被引：0
|
作者：
Bulak, E
Varnah, T
Paetzold, P [1 ]
Englert, U
机构：
[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany
[2] Bogazici Univ, Dept Chem, Istanbul, Turkey
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 01期
关键词：
hydroboration; iminoborane; crystal structure;
D O I：
10.1002/(SICI)1521-3749(199901)625:1<3::AID-ZAAC3>3.0.CO;2-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The formation of four products of the type Me3C(Me3Si)N=BH-N(CMe3)=BR2' [BR2' = B(CHMeiPr)(2) (1), B(c-C6H11)(2) (2), B(C8H14) (3), B(O2C6H4) (4)] from the iminoborane Me3C(Me3Si)N - B double bond N(CMe3) and the hydroboranes (R-2'BH)(2) is described. Crystal structure analysis reveals the molecule 1 to have an N=B-N=B backbone with two orthogonal N=B bond planes and, hence, no conjugation between the two B-N double bonds.
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页码：3 / 5
页数：3
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