Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ2 N3:N3′]diformatomanganese(II)]

被引：0

作者：

Chen, Shui-Sheng ^{[1
]}

Yang, Sen-Lin ^{[1
]}

Zhang, Shu-Ping ^{[1
]}

Lu, Zi-Qiang ^{[2
]}

机构：

[1] Fuyang Normal Coll, Dept Chem, Fuyang 236041, Anhui, Peoples R China

[2] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci, Luoyang 471022, Henan, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

1,4-BIS(IMIDAZOL-1-YLMETHYL)BENZENE; POLYROTAXANE; BIX;

D O I：

10.1107/S1600536810044053

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Mn(CHO2)(2)(C12H10N4)(2)](n), the Mn-II atom and the benzene ring of the ligand lie on an inversion centers. The Mn-II atom has an octahedral coordination environment composed of four N atoms from two different symmetry-related N-heterocyclic ligands forming the basal plane, and two O atoms from symmetry-related formate anions occupying the apical positions. The title compound forms a two-dimensional (4,4) net parallel to (100) with all the Mn-II atoms lying on a plane. The crystal structure is consolidated by intermolecular N-H center dot center dot center dot O hydrogen bonds..

引用

页码：M1501 / U218

页数：12

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