Titanium isopropoxide complexes containing diamine bis-thiolato based [N2S2]2- ligands; effect of steric bulk on coordination features

被引：7

作者：

Shaban, Shaban Y. ^{[1
]}

Ramadan, Abd El-Motaleb M. ^{[1
]}

Heinemann, Frank W. ^{[2
]}

机构：

[1] Kafrelsheikh Univ, Fac Sci, Dept Chem, Kafrelsheikh 33516, Egypt

[2] Univ Erlangen Nurnberg, Inst Inorgan Chem, D-91054 Erlangen, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 20卷

关键词：

Titanium complexes; Structure; Bis-thiolato complexes; Amide coordination; Thiolate oxidation; Hydrolysis; BIS(PHENOLATO) LIGANDS; CANCER-TREATMENT; METAL-COMPLEXES; ZINC-COMPLEXES; VANADIUM; CYTOTOXICITY; DISULFIDE;

D O I：

10.1016/j.inoche.2012.02.035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two dianionic amine bis(thiolato) ligands are introduced and their reactions with titanium tetra(iso-propoxide) studied; ligand N2H2S2 - H-2 (1) having NH donor groups leads exclusively to dinuclear [{Ti(N2H2S2)((OPr)-Pr-i)}(2)] (2) along with an oxidation product of the ligand (3) whereas ligand N2Me2S2 - H-2 (4) having an additional N-substituent leads exclusively to a mononuclear [Ti(N2Me2S2)((OPr)-Pr-i)(2))] (5) type complex. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：135 / 137

页数：3

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