Direct synthesis of sulfonated poly(phthalazinone ether) for proton exchange membrane via N-C coupling reaction

被引：17
|
作者：
Chen, YL
Meng, YZ [1 ]
Hay, AS
机构：
[1] Sun Yat Sen Univ, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China
[2] Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Peoples R China
[3] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
来源：
POLYMER | 2005年 / 46卷 / 24期
基金：
中国国家自然科学基金;
关键词：
sulfonation; polyaromatics; polycondensation;
D O I：
10.1016/j.polymer.2005.08.077
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Sulfonated poly(phthalazinone ether)s 7a-f were directly synthesized by aromatic nucleophilic polycondensation of bisphthalazinone 4 with the mixture of sulfonated dihalide 5 and non-modified dihalide 6 via N-C coupling reaction. The sulfonated polymers were characterized by H-1 NMR, elemental analysis and other technologies. Because of their specially designed molecular structure, the novel sulfonated polymers showed excellent thermal and oxidative stability. The sulfonated polymers also had reasonable water affinity and moderate proton conductivity for the usage in proton exchange membrane fuel cells. [GRAPHICS] (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：11125 / 11132
页数：8
相关论文
共 50 条
  • [1] Novel synthesis of sulfonated poly(phthalazinone ether ketone) used as a proton exchange membrane via N-C coupling reaction
    Chen, YL
    Meng, YZ
    Hay, AS
    [J]. MACROMOLECULES, 2005, 38 (09) : 3564 - 3566
  • [2] Synthesis and characterization of phthalazinone containing poly(arylene ether)s via a novel N-C coupling reaction
    Wang, SJ
    Meng, YZ
    Tjong, SC
    Hlil, AR
    Hay, AS
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (16) : 2481 - 2490
  • [3] SYNTHESIS AND CHARACTERIZATION OF POLY(PHTHALAZINONE ETHER PHOSPHINE OXIDE)S BY N-C COUPLING REACTION
    程琳
    [J]. Chinese Journal of Polymer Science, 2010, (02) : 287 - 290
  • [4] Synthesis and characterization of poly(phthalazinone ether phosphine oxide)s by N-C coupling reaction
    Bin Jing
    Jia-xi Wang
    Xiao-yan Li
    Hui-ying Shi
    Xiao-wei Hou
    Xing-quan Xiong
    Lin Cheng
    [J]. Chinese Journal of Polymer Science, 2010, 28 : 287 - 290
  • [5] Synthesis and characterization of poly(phthalazinone ether phosphine oxide)s by N-C coupling reaction
    Jing, Bin
    Wang, Jia-xi
    Li, Xiao-yan
    Shi, Hui-ying
    Hou, Xiao-wei
    Xiong, Xing-quan
    Cheng, Lin
    [J]. CHINESE JOURNAL OF POLYMER SCIENCE, 2010, 28 (02) : 287 - 290
  • [6] Synthesis and characterization of sulfonated poly(phthalazinone ether ketone) for proton exchange membrane materials
    Gao, Y
    Robertson, GP
    Guiver, MD
    Jian, XG
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (04) : 497 - 507
  • [7] Synthesis and characterization of sulfonated poly(phthalazinone ether nitrile ketone)s for proton exchange membrane
    Wang, GQ
    Zhu, XL
    Zhang, SH
    Liang, YF
    Jian, XG
    [J]. ACTA POLYMERICA SINICA, 2006, (02): : 209 - 212
  • [8] Direct copolymerization of sulfonated poly(phthalazinone arylene ether)s for proton-exchange-membrane materials
    Gao, Y
    Robertson, GP
    Guiver, MD
    Jian, XG
    Mikhailenko, SD
    Wang, KP
    Kaliaguine, S
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (17) : 2731 - 2742
  • [9] Poly(phthalazinone ether ketone) ionomers synthesized via N-C coupling reaction for fuel cell applications
    Chen, YL
    Meng, YZ
    Li, XH
    Hay, AS
    [J]. MACROMOLECULES, 2005, 38 (24) : 10007 - 10013
  • [10] Synthesis and characterization of sulfonated poly(phthalazinone ether phosphine oxide)s by direct polycondensation for proton exchange membranes
    Ma, Xuhui
    Zhang, Chunjie
    Xiao, Guyu
    Yan, Deyue
    Sun, Guoming
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (05) : 1758 - 1769
12345