Preparation of the enantiomers of an N-methylpyrrole analogue of Troger's base

被引：19
|
作者：
Valík, M
Dolensky, B
Herdtweck, E
Král, V
机构：
[1] Inst Chem Technol Prague, Dept Analyt Chem, Prague 11628 6, Czech Republic
[2] Tech Univ Munich, Dept Inorgan Chem, D-85747 Garching, Germany
来源：
TETRAHEDRON-ASYMMETRY | 2005年 / 16卷 / 11期
关键词：
D O I：
10.1016/j.tetasy.2005.04.016
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The enantiomers of bis(1-phenylethyl)-4,9-methano-1,6-dimethyl-4,5,9,10-tetrahydro-1H,6H-dipyrrolo-[3,2-b:3',2'-f][1,5]-diazocin-2.7-dicarboxlate were obtained by crystallization-induced asymmetric transformation (CIAT). The CIAT was driven by the absolute configuration of the 1-phenylethyl groups present in their convalent structure. Thus, the first example of CIAT on Troger's base derivatives in the absence of a resolving agent is reported. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1969 / 1974
页数：6
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