A quasi-solid-state dye-sensitized solar cell based on porous polymer electrolyte membrane

被引：15

作者：

Zhang, Xiao ^{[1
,2
]}

Wang, Cong-Xiao ^{[1
,2
]}

Li, Fu-You ^{[3
]}

Xia, Yong-Yao ^{[1
,2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

[3] Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2008年 / 194卷 / 01期

关键词：

quasi-solid-state dye-sensitized solar cell; gel polymer electrolyte; porous membrane;

D O I：

10.1016/j.jphotochem.2007.07.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Water was employed as plasticizer to produce porous polymer membrane. The gel polymer electrolyte containing 72% liquid organic electrolyte (0.5 M LiI, 0.05 M I-2, 0.5 M 4-tert-butylpyridine in PC) shows ionic conductivity of 6.4 x 10(-4) S cm(-1) due to its high porous structure. Moreover, the porous electrolyte membrane shows good mechanical strength and serves as a separator in the solar cells. Quasi-solid-state solar cells fabricated with this gel electrolyte displayed energy conversion efficiency of 6.0% when the cell gap was tuned to 30 pm. Moreover, these cells possessed much better long-term stability compared with those based on liquid organic electrolyte. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：31 / 36

页数：6

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