Self-template biomass-derived nitrogen and oxygen co-doped porous carbon for symmetrical supercapacitor and dye adsorption

被引:89
|
作者
Sun, Zhe [1 ]
Qu, Keqi [1 ]
Li, Jiahang [1 ]
Yang, Shuai [1 ]
Yuan, Bingnan [1 ,2 ]
Huang, Zhanhua [1 ]
Guo, Zhanhu [2 ]
机构
[1] Northeast Forestry Univ, Coll Mat Sci & Engn, Key Lab Biobased Mat Sci & Technol, Minist Educ, Harbin 150040, Peoples R China
[2] Univ Tennessee, Dept Chem & Bimol Engn, Integrated Composites Lab ICL, Knoxville, TN 37996 USA
基金
中国国家自然科学基金;
关键词
Corncob; Porous carbon; Supercapacitor; Electrode; Adsorption; ELECTRODES; CELLULOSE; HEMICELLULOSE; ACTIVATION; PYROLYSIS;
D O I
10.1007/s42114-021-00352-8
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Exploring high-efficiency, green, low-cost, and sustainable biomass waste materials to solve energy shortage and environmental contamination issues is still a significant challenge. Herein, self-template corncob porous carbon (CPC) with bifunctions, high oxygen (16.34 at%), and nitrogen content (2.30 at%) was obtained by a simple carbonization-activation method. Benefiting from the high specific surface area, porous structure and high oxygen and nitrogen content of the prepared CPC, the optimal CPC-700-2 exhibited a higher special capacitance of 295.93 F g(-1) at the current density of 1 A g(-1), good rate capability (170 F g(-1) at 50 A g(-1)), and excellent stability and circularity. Significantly, the CPC-based symmetric supercapacitor demonstrated a high energy density (9.9 Wh kg(-1)) at a power density of 250 W kg(-1), and exceptional cyclic stability. More interestingly, the CPC also has an efficient sewage purification capacity. The adsorption test confirmed that the CPC possesses a higher adsorption capacity and removal rate for Rh B (249.06 mg g(-1) and 99.87%). This satisfactory performance provides a potential way for the high value-added utilization of agricultural and forestry waste.
引用
收藏
页码:1413 / 1424
页数:12
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