Promising biomass-derived nitrogen-doped porous carbon for high performance supercapacitor

被引:36
|
作者
Zhou, Jiangqi [1 ]
Wang, Min [1 ]
Li, Xin [1 ]
机构
[1] Beijing Inst Technol, Sch Chem & Chem Engn, Beijing 100081, Peoples R China
关键词
Biomass; Carbon materials; Porous materials; Facile preparation; Supercapacitors; CAPACITY BATTERY ANODES; HIGH-SURFACE-AREA; SUSTAINABLE PRECURSORS; SUPERIOR PERFORMANCE; ACTIVATED CARBON; GRAPHENE; NANOSHEETS; ELECTRODES; OXYGEN; OXIDE;
D O I
10.1007/s10934-018-0622-3
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
We proposed a simple strategy of one-pot carbonization, activation and nitrogen-doped processes to prepare biomass-derived nitrogen-doped porous carbon (NPC-K) by using well-sourced dumpling flour as carbon precursor, urea as nitrogen precursor and KOH as activation agent. In this process, the combination of KOH and urea was used to construct a highly porous structure because of their synergistic effect. The as-prepared NPC-K exhibited honeycomb-like porous structure, large specific surface area (2853.6 m(2) g(-1)) and moderate nitrogen content. Therefore, the NPC-K displayed maximum specific capacitance of 311 F g(-1) at 1 A g(-1), outstanding rate capability and long lifetime of 10000 cycles in 6M KOH. Furthermore, NPC-K based symmetrical supercapacitor presented a high energy density of 15.92 Wh kg(-1). These results are superior to many previously reported carbon materials.
引用
收藏
页码:99 / 108
页数:10
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