Synthesis of Amines by Reductive Amination of Aldehydes and Ketones using Co3O4/NGr@C Catalyst

被引：59

作者：

Pisiewicz, Sabine ^{[1
]}

Stemmler, Tobias ^{[1
]}

Surkus, Annette-Enrica ^{[1
]}

Junge, Kathrin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

CHEMCATCHEM | 2015年 / 7卷 / 01期

关键词：

reductive amination; aldehyde; ketone; heterogeneous catalysis; cobalt catalyst; ONE-POT; BORANE;

D O I：

10.1002/cctc.201402527

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Heterogenized non-noble metal-based catalysts allow for cost-efficient and environmentally benign hydrogenations. Here, we have developed a straightforward reductive amination methodology using molecular hydrogen in the presence of a Co3O4/NGr@C catalyst system. Various carbonyl compounds were transformed with secondary amines to the corresponding tertiary amines with good to excellent yields and selectivity. The Co3O4/NGr@C catalyst is recycled up to five times without significant loss of activity.

引用

页码：62 / 64

页数：3

共 50 条

[11] Selective synthesis of secondary amines by Pt nanowire catalyzed reductive amination of aldehydes and ketones with ammonia
Qi, Fenqiang
Hu, Lei
Lu, Shuanglong
Cao, Xueqin
Gu, Hongwei
CHEMICAL COMMUNICATIONS, 2012, 48 (77) : 9631 - 9633
[12] Solvent- and catalyst-free direct reductive amination of aldehydes and ketones with Hantzsch ester: synthesis of secondary and tertiary amines
Quynh Pham Bao Nguyen
Kim, Taek Hyeon
TETRAHEDRON, 2013, 69 (24) : 4938 - 4943
[13] Reductive amination of aldehydes and ketones by NaBH4 using carbon-based solid acid (CBSA) as catalyst
Shokrolahi, Arash
Zali, Abbas
Keshavarz, Mohammad Hossein
GREEN CHEMISTRY LETTERS AND REVIEWS, 2011, 4 (03) : 195 - 203
[14] Flow synthesis of secondary amines over Ag/Al2O3 catalyst by one-pot reductive amination of aldehydes with nitroarenes
Artiukha, Ekaterina A.
Nuzhdin, Alexey L.
Bukhtiyarova, Galina A.
Bukhtiyarov, Valerii I.
RSC ADVANCES, 2017, 7 (72): : 45856 - 45861
[15] Reductive-hydroformylation of 1-octene to nonanol using fibrous Co3O4 catalyst
Bhagade, Sachin S.
Chaurasia, Shivkumar R.
Bhanage, Bhalchandra M.
CATALYSIS TODAY, 2018, 309 : 147 - 152
[16] Direct reductive amination and selective 1,2-reduction of α,β-unsaturated aldehydes and ketones by NaBH4 using H3PW12O40 as catalyst
Heydari, Akbar
Khaksar, Samad
Akbari, Jafar
Esfandyari, Maryam
Pourayoubi, Mehrdad
Tajbakhsh, Mahmoud
TETRAHEDRON LETTERS, 2007, 48 (07) : 1135 - 1138
[17] BF3•Et2O as a metal-free catalyst for direct reductive amination of aldehydes with amines using formic acid as a reductant
Luo, Zhenli
Pan, Yixiao
Yao, Zhen
Yang, Ji
Zhang, Xin
Liu, Xintong
Xu, Lijin
Fan, Qing-Hua
GREEN CHEMISTRY, 2021, 23 (14) : 5205 - 5211
[18] ASYMMETRIC-SYNTHESIS OF AMINES BY THE REDUCTIVE AMINATION OF KETONES USING (+) AND (-) NOREPHEDRINE FOLLOWED BY PERIODATE-OXIDATION
SREEKUMAR, R
PILLAI, CN
TETRAHEDRON-ASYMMETRY, 1993, 4 (09) : 2095 - 2100
[19] Synthesis of unsaturated secondary amines by direct reductive amination of aliphatic aldehydes with nitroarenes over Au/Al2O3 catalyst in continuous flow mode
Nuzhdin, A. L.
Artiukha, E. A.
Bukhtiyarova, G. A.
Zaytsev, S. Yu
Plyusnin, P. E.
Shubin, Yu V.
Bukhtiyarov, V. I.
RSC ADVANCES, 2016, 6 (91): : 88366 - 88372
[20] The direct reductive amination of electron-deficient amines with aldehydes: the unique reactivity of the Re2O7 catalyst
Das, Braja Gopal
Ghorai, Prasanta
CHEMICAL COMMUNICATIONS, 2012, 48 (66) : 8276 - 8278

← 1 2 3 4 5 →