Ni-Catalyzed Allylic Dearomatization Reaction of β-Naphthols with Allylic Alcohols

被引：26

作者：

Zhang, Hui-Jun ^{[1
]}

Gu, Qing ^{[2
]}

You, Shu-Li ^{[1
,2
]}

机构：

[1] East China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

ORGANIC LETTERS | 2020年 / 22卷 / 08期

基金：

国家重点研发计划;

关键词：

CROSS-COUPLING REACTIONS; ASYMMETRIC DEAROMATIZATION; GRIGNARD-REAGENTS; ENANTIOSELECTIVE DEAROMATIZATION; INTRAMOLECULAR DEAROMATIZATION; SUBSTITUTION-REACTIONS; BOND FORMATION; ALKYLATION; ALLYLATION; PALLADIUM;

D O I：

10.1021/acs.orglett.0c01109

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ni-catalyzed intermolecular allylic dearomatization reaction of beta-naphthols with allylic alcohols was achieved. By utilizing Ni(cod)(2) as a catalyst precursor, DPEphos as a ligand and 4 angstrom molecular sieves as additives, the dearomatization reaction of beta-naphthols with aryl allylic alcohols proceeded smoothly under mild conditions, affording the desired beta-naphthalenone products bearing a quaternary carbon center in moderate to good yields with excellent linear selectivity.

引用

页码：3297 / 3301

页数：5

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