Oxidation of copper in the presence of the organic metal polyaniline

被引：18
|
作者：
Posdorfer, J [1 ]
Wessling, B [1 ]
机构：
[1] Ormecon Chem GMBH & Co KG, D-22949 Ammersbek, Germany
来源：
SYNTHETIC METALS | 2001年 / 119卷 / 1-3期
关键词：
polyaniline; copper oxides; chronopotentiometric reduction; SEM images;
D O I：
10.1016/S0379-6779(00)01393-X
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
By immersing copper in a water dispersion of the Organic Metal (OM) polyaniline (PAni) a thin layer is adsorbed at the surface forming a Cu(I)-PAni complex. XPS analysis showed only Cu(I) signals. Upon aging, the PAni treated Cu surface shows an exponentially decreasing Cu2O layer, and an increase of CuO with roott. An acid etched Cu surface shows a linear increase of both Cu2O and CuO. The PAni treatment passivates Cu. The role of polyaniline in the passivation process of copper is discussed and kinetic data are presented.
引用
收藏
页码：363 / 364
页数：2
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