Blackening of aza-BODIPY analogues by simple dimerization: panchromatic absorption of a pyrrolopyrrole aza-BODIPY dimer

被引：42

作者：

Kage, Yuto ^{[1
]}

Mori, Shigeki ^{[2
]}

Ide, Marina ^{[3
]}

Saeki, Akinori ^{[3
]}

Furuta, Hiroyuki ^{[1
,4
]}

Shimizu, Soji ^{[1
,4
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8190395, Japan

[2] Ehime Univ, Adv Res Support Ctr ADRES, Matsuyama, Ehime 7908577, Japan

[3] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[4] Kyushu Univ, CMS, Fukuoka 8190395, Japan

来源：

MATERIALS CHEMISTRY FRONTIERS | 2018年 / 2卷 / 01期

关键词：

PUSH-PULL OLIGOTHIOPHENES; SOLAR-CELLS; PORPHYRIN DIMER; DESIGN; FLUORESCENCE; CONJUGATION; RELAXATION; MOLECULES;

D O I：

10.1039/c7qm00438a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimerization of the so-called pyrrolopyrrole aza-BODIPY, which is a new class of aza-BODIPY analogues exhibiting intense absorption and emission in the visible (Vis) and near infrared (NIR) region, via a bithienyl linkage led to the creation of a novel black dye with dual emission and panchromatic absorption properties in the Vis/NIR region. The role of the linkage in the dye was unambiguously elucidated by comparison of the optical properties with those of its biphenyl-linked counterpart.

引用

页码：112 / 120

页数：9

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