Blackening of aza-BODIPY analogues by simple dimerization: panchromatic absorption of a pyrrolopyrrole aza-BODIPY dimer

被引：42
|
作者：
Kage, Yuto [1 ]
Mori, Shigeki [2 ]
Ide, Marina [3 ]
Saeki, Akinori [3 ]
Furuta, Hiroyuki [1 ,4 ]
Shimizu, Soji [1 ,4 ]
机构：
[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8190395, Japan
[2] Ehime Univ, Adv Res Support Ctr ADRES, Matsuyama, Ehime 7908577, Japan
[3] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[4] Kyushu Univ, CMS, Fukuoka 8190395, Japan
来源：
MATERIALS CHEMISTRY FRONTIERS | 2018年 / 2卷 / 01期
关键词：
PUSH-PULL OLIGOTHIOPHENES; SOLAR-CELLS; PORPHYRIN DIMER; DESIGN; FLUORESCENCE; CONJUGATION; RELAXATION; MOLECULES;
D O I：
10.1039/c7qm00438a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dimerization of the so-called pyrrolopyrrole aza-BODIPY, which is a new class of aza-BODIPY analogues exhibiting intense absorption and emission in the visible (Vis) and near infrared (NIR) region, via a bithienyl linkage led to the creation of a novel black dye with dual emission and panchromatic absorption properties in the Vis/NIR region. The role of the linkage in the dye was unambiguously elucidated by comparison of the optical properties with those of its biphenyl-linked counterpart.
引用
收藏
页码：112 / 120
页数：9
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