Kinetics and mechanism of Ru(III) catalysed oxidation of α-picolines by Ce(IV) in nitric acid medium

被引：0

作者：

Rao, MA ^{[1
]}

Rao, NVB ^{[1
]}

机构：

[1] Osmania Univ, Dept Chem, Hyderabad 500007, Andhra Pradesh, India

来源：

OXIDATION COMMUNICATIONS | 2003年 / 26卷 / 04期

关键词：

kinetics; oxidation; alpha-picolines; catalysis; mechanism;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of oxidation of alpha-picolines by Ce(IV) in the presence of Ru(III) in aqueous nitric acid medium has been studied. The order in [Ce(IV)] was found to be unity and with respect to [picoline] it was fractional. Increase in [Ru(III)] increased the rate of oxidation and order in [Ru(III)] was found to be fractional. The rate of oxidation increased with increase in [H+] and order with respect to [H+] was also fractional. These reactions have been studied at different temperatures and the energy of activation has been determined from which thermodynamic parameters have been evaluated. Isokinetic temperature was found to be much above the range of experimental temperature used. A plausible mechanism consistent with the experimental results has been proposed.

引用

页码：580 / 585

页数：6

共 50 条

[31] Kinetics and mechanism of iridium(III) catalysed oxidation of ethanol by cerium(IV) in aqueous sulphuric acid media
Mohanty, RK
Das, M
Das, AK
[J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1998, 37 (01): : 34 - 40
[32] Kinetics and mechanism of chromium(III)-catalysed oxidation of ethanol by cerium(IV) in aqueous sulphuric acid media
Das, AK
Mondal, SK
Kar, D
[J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1998, 37 (12): : 1102 - 1105
[33] Kinetics and mechanism of iridium(III) catalysed oxidation of methanol by cerium(IV) in aqueous sulfuric acid media
Das, AK
[J]. JOURNAL OF CHEMICAL RESEARCH, 1996, (04) : 184 - +
[34] Kinetics and mechanism of iridium(III) catalysed oxidation of formaldehyde by cerium(IV) in aqueous sulfuric acid media
Kar, D
Mondal, SK
Das, M
Das, AK
[J]. JOURNAL OF CHEMICAL RESEARCH-S, 1998, (07): : 394 - +
[35] KINETICS OF OXIDATION OF GLYCOLIC ACID BY CE(IV) IN SULFURIC-ACID MEDIUM
PRASAD, S
CHOUDHARY, J
[J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1979, 17 (02): : 167 - 169
[36] Kinetics and mechanism of ruthenium (III)-catalysed oxidation of pyrimidine bases by peroxydiphosphate in aqueous perchloric acid medium
Latha, BS
Adinarayana, M
Rao, PJ
[J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1999, 38 (11): : 1184 - 1187
[37] Kinetics and mechanism of osmium (VIII) catalysed oxidation of formic acid by hexacyanoferrate (III) in aqueous alkaline medium
Sharma, G
Binyahia, AR
Sharma, PD
[J]. JOURNAL OF CHEMICAL RESEARCH, 2000, (05) : 213 - 213
[38] Kinetics and mechanism of the plutonium catalysed nitric acid oxidation of U(IV) ions in 30% tributyl phosphate solution
Koltunov, V. S.
Zhuravleva, G. I.
Marchenko, V. I.
Dvoeglazov, K. N.
Savilova, O. A.
Koltunov, G. V.
Taylor, R. J.
Bankhead, M.
[J]. RADIOCHIMICA ACTA, 2007, 95 (10) : 559 - 567
[39] Kinetics and mechanism of ruthenium(III)-catalysed oxidation of dimethylformamide by periodate in alkaline medium
Timmanagoudar, PL
Hiremath, GA
Nandibewoor, ST
[J]. JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1997, 74 (04) : 296 - 298
[40] Oxidation of Ce(III) to Ce(IV) by Ozone in Nitric Acid Medium Using a Static Mixer: Mathematical Modeling and Experimental Validation
Singh, Sukhdeep
Vincent, Tessy
Bhaskarwar, Ashok N.
Makwana, Trushit
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2017, 56 (40) : 11422 - 11434

← 1 2 3 4 5 →