Polycyclic Aromatic Hydrocarbons (PAHs) in Indoor Dust Across China: Occurrence, Sources and Cancer Risk Assessment

In this study, the occurrence of 16 polycyclic aromatic hydrocarbons (PAHs) was investigated in 31 household dusts that were sampled from 27 areas located in 10 provinces, China. The total concentrations of PAHs ( n-ary sumation PAHs) were in the range of 613-10,111 ng center dot g(-1) with a median of 2565 ng center dot g(-1). The predominant PAHs were 2 to 3 ringed compounds, accounting for 85.3% of n-ary sumation PAHs. The geographical location had little impact on the contents of PAHs. Higher concentrations of n-ary sumation PAHs and individual homologues of PAHs except for naphthalene (NAP) were observed in rural areas, which is related to the higher usage of coal or biomass for cooking. Cooking method played a major role in contributing to the concentrations of PAHs. Both household cooking and petrogenic sources from outdoors were the primary sources of PAHs in household dust. Cancer risk assessment indicated that dermal contact and ingestion are the main exposure pathways to indoor residents. Furthermore, the average values of sum of incremental lifetime cancer risks (ILCRs) were 2.22 x 10(-7) for adults and 2.51 x 10(-7) for children, suggesting that there is a low health risk posed by PAHs in indoor dust. The contribution percentage of 4 to 6 rings PAHs to ILCRs was up to 96.3%, indicating that higher molecular weight PAHs in indoor dust, especially benzo[a]pyrene (BaP) and dibenzo[a,h]anthracene (DahA), are major factors contributing to cancer risk.