Intramolecular Hydroamination of Aminoalkenes Catalyzed by a Cationic Zirconium Complex

被引：36

作者：

Wang, Xinke ^{[1
]}

Chen, Zhou ^{[1
]}

Sun, Xiu-Li ^{[1
]}

Tang, Yong ^{[1
]}

Xie, Zuowei ^{[2
,3
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

[2] Chinese Univ Hong Kong, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai Inst Organ Chem, Shatin, Hong Kong, Peoples R China

[3] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 18期

基金：

中国国家自然科学基金;

关键词：

ASYMMETRIC HYDROAMINATION; TRIDENTATE LIGANDS; ETHYLENE; POLYMERIZATION; ALKENES; BEARING; AMINES; COPOLYMERIZATION; IMIDO; ALKYL;

D O I：

10.1021/ol201731m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new cationic [N-O-S]zirconium complex (cat.) was developed to be an excellent catalyst for the intramolecular hydroamination of aminoalkenes with a large substrate scope from terminal alkenes to internal alkenes, and primary amines to secondary amines. The catalyst system can also tolerate various functional groups and perform sequential hydroamination of primary aminodienes.

引用

页码：4758 / 4761

页数：4

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