Nickel(0) complexes of a 1-zirconacyclopent-3-yne

被引：22
|
作者：
Bach, MA [1 ]
Burlakov, VV [1 ]
Arndt, P [1 ]
Baumann, W [1 ]
Spannenberg, A [1 ]
Rosenthal, U [1 ]
机构：
[1] Univ Rostock eV, Leibniz Inst Organ Katalyse, D-18059 Rostock, Germany
来源：
ORGANOMETALLICS | 2005年 / 24卷 / 13期
关键词：
D O I：
10.1021/om050148x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complexation of the uncommon 1-zirconacyclopent-3-yne Cp2Zr(eta(4)-H2C4H2) by Ni(0) complexes is described and compared to the coordination of similar 1-metallacyclopenta-2,3,4-trienes Cp2M(eta(4)-PhC4Ph) of titanium and zirconium, both showing mu-"cis"-complexation of 1,2,3-butatrienes and 1,3-butadiynes in addition to the well-known mu-"trans"-complexation.
引用
收藏
页码：3047 / 3052
页数：6
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