Synthesis and characterization of soluble porphyrazines bearing octakis 2-anthraquinonylmethylthio substituents

被引：2

作者：

Ipek, Tugba ^{[1
]}

Gonca, Ergun ^{[1
]}

机构：

[1] Fatih Univ, Dept Chem, TR-34500 Istanbul, Turkey

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 64卷 / 05期

关键词：

2-(Chloromethyl)anthraquinone; Porphyrazine; Maleonitrile; Copper; Zinc; SPECTRAL PROPERTIES; SECO-PORPHYRAZINES; DERIVATIVES; PHTHALOCYANINES; MACROCYCLES; MAGNESIUM; MOIETIES; UNITS;

D O I：

10.1080/00958972.2011.555539

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By cyclotetramerization of 1,2-bis(2-anthraquinonylmethylthio)maleonitrile in the presence of magnesium butanolate, magnesium porphyrazinate carrying eight (2-anthraquinonylmethylthio) functional groups on peripheral positions has been synthesized. The metal-free derivative was obtained by treatment with trifluoroacetic acid; reaction of this product with copper(II) acetate, zinc(II) acetate, and cobalt(II) acetate led to the metal porphyrazinates [M = Cu(II), Zn(II), and Co(II)]. These new compounds have been characterized by elemental analysis, together with FT-IR, H-1-NMR, C-13-NMR, UV-Vis, and mass spectral data.

引用

页码：795 / 804

页数：10

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