Total synthesis of (±) Xyloketal H

被引：5
|
作者：
Bhosale, Viraj A. [1 ]
Kulkarni, Mukund G. [1 ]
机构：
[1] Savitribai Phule Pune Univ, Dept Chem, Pune 411007, Maharashtra, India
来源：
TETRAHEDRON LETTERS | 2015年 / 56卷 / 20期
关键词：
Claisen rearrangement; Grignard; Oxidation; Ozonolysis; Wittig olefination; FUNGUS XYLARIA SP; METHIDE INTERMEDIATE GENERATION; NATURAL-PRODUCTS; BIOMIMETIC SYNTHESIS; EFFICIENT METHOD; METABOLITE; CORE;
D O I：
10.1016/j.tetlet.2015.03.118
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient total synthesis of (+/-) Xyloketal H is described, the Wittig olefination-Claisen rearrangement protocol has served here as the key transformation for constructing the core structure of the metabolite. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2568 / 2570
页数：3
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