Interdimensional degeneracies in van der Waals clusters and quantum Monte Carlo computation of rovibrational states

被引:13
|
作者
Nightingale, MP [1 ]
Moodley, M
机构
[1] Univ Rhode Isl, Dept Phys, Kingston, RI 02881 USA
[2] Univ KwaZulu Natal, Sch Phys, Howard Coll, ZA-4041 Durban, South Africa
来源
JOURNAL OF CHEMICAL PHYSICS | 2005年 / 123卷 / 01期
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.1941107
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Quantum Monte Carlo estimates of the spectrum of rotationally invariant states of noble gas clusters suggest interdimensional degeneracy in N-1 and N+1 spatial dimensions. We derive this property by mapping the Schrodinger eigenvalue problem onto an eigenvalue equation in which D appears as a continuous variable. We discuss implications for quantum Monte Carlo and dimensional scaling methods. (c) 2005 American Institute of Physics.
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页数:7
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