Highly regio- and enantioselective catalytic asymmetric hydroboration of α-substituted styrenyl derivatives

被引：70

作者：

Mazet, Clement ^{[1
]}

Gerard, David ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 01期

关键词：

1,1-DISUBSTITUTED ALKENES; TERMINAL ALKENES; HYDROGENATION; FUNCTIONALIZATION; TRANSFORMATIONS; VINYLARENES; COMPLEXES;

D O I：

10.1039/c0cc01547d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic asymmetric hydroboration of a variety of 1,1-disubstituted olefins has been achieved with excellent yields, perfect regioselectivity and in some cases, high levels of enantio-selectivity using readily accessible iridium catalyst.

引用

页码：298 / 300

页数：3

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