Magnetic properties of SmCo7/Co and Sm(Co,Fe)7/α-(Fe,Co) nanocomposite magnets prepared by magnetic annealing

The effect of applying a magnetic field during the crystallization process of mechanically milled SmCo9.5 and Sm(Co0.88Fe0.12)(9.5) alloys on the nanostructure, exchange coupling, and magnetic properties has been studied. Compared with samples annealed without the agnetic' field, there was a noticeable improvement in the intrinsic coercivity H-i(c), the remanence B-r, and the maximum magnetic energy product (BH)(max) for SmCo9.5 and Sm(Co0.88Fe0.12)(9.5) alloys annealed in a 10 kOe field. An improvement of 31.5% of (BH)(max) was obtained for SmCo9.5 alloy after the magnetic, annealing. Better rectangularity of the demagnetization curves was also observed for SmC9.5 and Sm(Co0.88Fe0.12)(9.5) after the magnetic alloys annealing. The improvement in the magnetic properties after magnetic annealing is considered to be the result of enhanced exchange coupling, resulting from modifications of nanostructure induced by the magnetic field during the crystallization process of the mechanically milled alloys in a nearly perfect amorphous state.