Magnesium-Antimony Liquid Metal Battery for Stationary Energy Storage

被引:246
|
作者
Bradwell, David J. [1 ]
Kim, Hojong [1 ]
Sirk, Aislinn H. C. [1 ]
Sadoway, Donald R. [1 ]
机构
[1] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA
关键词
ALLOYS;
D O I
10.1021/ja209759s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Batteries are an attractive option for grid: scale energy storage applications because of their small footprint and flexible siting. A high-temperature (700 degrees C) magnesium antimony (MgllSb) liquid metal battery comprising a negative electrode of Mg, a molten salt electrolyte (MgCL2-KCl-NaCl), and a positive electrode of Sb is proposed and characterized. Because of the immiscibility of the contiguous salt and metal phases, they stratify by density into three distinct layers. Cells were cycled at rates ranging from 50 to 200 mA/cm(2) and demonstrated up to 69% DC-DC energy efficiency. The self-segregating nature of the battery components and the use Of low-cost materials results in a promising technology for stationary energy storage applications.
引用
收藏
页码:1895 / 1897
页数:3
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