Preparation, crystal structure, and magnetism of [(CH3)2NH2][NdCl4(H2O)2]

被引：0
|
作者：
Becker, A [1 ]
Urland, W [1 ]
机构：
[1] Univ Hannover, Inst Anorgan Chem, D-30167 Hannover, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 02期
关键词：
dimethylammonium diaquatetrachloroneodymate; crystal structure; magnetic properties; angular overlap model;
D O I：
10.1002/(SICI)1521-3749(199902)625:2<217::AID-ZAAC217>3.0.CO;2-E
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex water containing chloride [(CH3)(2)NH2] [NdCl4(H2O)(2)] was prepared for the first time and the crystal structure was determined by X-ray methods from single crystals. The compound crystallizes in the orthorhombic space group Cmca (Z = 8) with a = 1793.5(2) pm, b = 936.6(2) pm and c = 1232.8(2) pm. The anionic part of the structure is built up by chains of edge connected [NdCl4/2Cl2(H2O)(2)](-) trigondodecahedra. In order to study the interactions between the neodymium cation and the ligands magnetic measurements were carried out. The magnetic data were interpreted by ligand field calculations applying the angular overlap model.
引用
收藏
页码：217 / 220
页数：4
相关论文
共 50 条
  • [11] Structure of [(CH3)2NH2]2CoCl4 at elevated temperatures
    Mahmoudkhani, Amir H.
    Langer, Vratislav
    Acta Crystallographica Section B: Structural Science, 1999, 55 (05): : 752 - 757
  • [12] Structure of [(CH3)2NH2]2CoCl4 at elevated temperatures
    Mahmoudkhani, AH
    Langer, V
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1999, 55 : 752 - 757
  • [13] CRYSTAL-STRUCTURE OF DIMETHYLAMMONIUMTRICHLOROCUPRATE, (CH3)2NH2(CUCL3)
    ECKARDT, K
    SVOBODA, I
    PABST, I
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1993, 208 : 253 - 254
  • [14] Synthesis, characterisation and crystal structure of [(CH3)2CH]2NH2(PhPO3H)2SnPh3
    Diop, Tidiane
    Diop, Libasse
    Molloy, Kieran C.
    Kociok-Koehn, Gabriele
    Fall, Djibril
    MAIN GROUP METAL CHEMISTRY, 2012, 35 (3-4) : 99 - 102
  • [15] THE STUDY OF SPONTANEOUS POLARIZATION OF [(CH3)2NH2]2CUCL4 CRYSTAL
    BOBROVA, ZA
    VARIKASH, VM
    ANDREEV, EF
    DOKLADY AKADEMII NAUK BELARUSI, 1988, 32 (09): : 787 - 789
  • [16] Crystal structure of triethylentetraammonium bis monohydrogenmonophosphate dihydrate, [NH3(CH2)2NH2(CH2)2NH2(CH2)2NH3](HPO4)2 · 2H2O
    Zakaria Elaoud
    Slaheddine Kamoun
    Tahar Mhiri
    Joel Jaud
    Journal of Chemical Crystallography, 1999, 29 : 541 - 545
  • [17] Crystal structure of triethylentetraammonium bis monohydrogenmonophosphate dihydrate, [NH3(CH2)2NH2(CH2)2NH2(CH2)2NH3](HPO4)2•2H2O
    Elaoud, Z
    Kamoun, S
    Mhiri, T
    Jaud, J
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1999, 29 (05) : 541 - 545
  • [18] NQR study of [(CH3)2NH2]3InBr6 and [4-ClC5H4NH]2InBr5(H2O)
    Ishihara, H.
    Nishi, H.
    Weiss, A.
    Journal of Molecular Structure, 345
  • [19] PREPARATION AND CRYSTAL-STRUCTURE OF SR(N3)2 . OS(CH3)2 . H2O
    TAEB, A
    KRISCHNER, H
    KRATKY, C
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1986, 176 (1-2): : 97 - 102
  • [20] [(CH3)2NH2]4[H4PMo12O40]Cl2•4H2O
    Wu, CD
    Lu, CZ
    Lin, X
    Yang, WB
    Zhuang, HH
    Huang, JS
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : m390 - m392
12345