Degradation of polystyrene using montmorillonite clay catalysts

被引：8
|
作者：
Jang, BS [1 ]
Cho, KH [1 ]
Kim, KH [1 ]
Park, DW [1 ]
机构：
[1] Pusan Natl Univ, Dept Chem Engn, Pusan 609735, South Korea
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2005年 / 86卷 / 01期
关键词：
polystyrene; catalytic degradation; montmorillonite clay; aromatics;
D O I：
10.1007/s11144-005-0297-z
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The performance of acid-treated montmorillonite catalysts in the degradation of polystyrene (PS) was investigated in this study. The degradation was carried out in a semi-batch reactor with a mixture of PS and catalyst at 400-450 degrees C. The commercial Sud Chemie acid-treated montmorillonite clays (K-series) showed good catalytic activity for the degradation of PS. The styrene monomer and ethylbenzene were major liquid products. The increase of surface acidity enhanced further cracking of styrene dimer and trimer to produce styrene monomer. Higher production of ethylbenzene for K30 may be related to its bigger pore volume and surface area compared to those of K5. High degradation temperature favored styrene monomer production.
引用
收藏
页码：75 / 82
页数：8
相关论文
共 50 条
  • [41] Synthesis and Characterization of Polystyrene-Montmorillonite Nanocomposite Particles Using an Anionic-Surfactant-Modified Clay and Their Friction Performance
    Yu, Chengcheng
    Ke, Yangchuan
    Deng, Qingchun
    Lu, Shichao
    Ji, Jingqi
    Hu, Xu
    Zhao, Yi
    APPLIED SCIENCES-BASEL, 2018, 8 (06):
  • [42] Thermal stability and degradation kinetics of polystyrene/organically- modified montmorillonite nanocomposites
    Department of Chemistry, Marquette University, Milwaukee, WI 53201-1881, United States
    不详
    J. Nanosci. Nanotechnol., 2008, 4 (1927-1936):
  • [43] Therma stabiliy and degradation kinetics of polystyrene/organically-modified montmorillonite nanocomposites
    Chigwada, Grace
    Kandare, Everson
    Wang, Dongyan
    Majoni, Stephen
    Mlambo, Darlington
    Wilkie, Charles A.
    Hossenlopp, Jeanne M.
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2008, 8 (04) : 1927 - 1936
  • [44] Esterification of dicarboxylic acids to diesters over Mn+-montmorillonite clay catalysts
    C. Ravindra Reddy
    Pushpa Iyengar
    Gopalpur Nagendrappa
    B. S. Jai Prakash
    Catalysis Letters, 2005, 101 : 87 - 91
  • [45] Esterification of dicarboxylic acids to diesters over Mn+-montmorillonite clay catalysts
    Reddy, CR
    Iyengar, P
    Nagendrappa, G
    Prakash, BSJ
    CATALYSIS LETTERS, 2005, 101 (1-2) : 87 - 91
  • [46] Triphase catalysis using montmorillonite clay/polymer intercalates
    Beach, Andrew
    Thompson, Nicholas
    Shabestary, Nahid
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [47] Oxidative degradation of aromatic N-compounds using cobalt containing montmorillonite-based catalysts
    Ilic, I.
    Milutinovic-Nikolic, A.
    Mojovic, Z.
    Vukovic, Z.
    Vulic, P.
    Grzetic, I
    Bankovic, P.
    Jovic-Jovicic, N.
    APPLIED CLAY SCIENCE, 2020, 193
  • [48] Chemical Modification of Poly(epichlorohydrin) Using Montmorillonite Clay
    Bekkar, Fatima
    Belbachir, Mohamed
    CHINESE JOURNAL OF CHEMISTRY, 2009, 27 (06) : 1174 - 1178
  • [49] Effect of the brush structure on the degradation mechanism of polystyrene-clay nanocomposites
    Chen, K
    Susner, MA
    Vyazovkin, S
    MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (09) : 690 - 695
  • [50] Thermal Degradation Kinetics of Polyurethane/Organically Modified Montmorillonite Clay Nanocomposites by TGA
    Pashaei, Shahryar
    Siddaramaiah
    Syed, Akheel Ahmed
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2010, 47 (08): : 777 - 783
12345