Two Zinc(II) Supramolecules Constructed from Imidazole Dicarboxylate: Synthesis, Structures, and Properties

被引：2
|
作者：
Sang, Yali [1 ]
Lin, Xuesong [1 ]
Sun, Weidong [1 ]
Yang, Suhua [1 ]
机构：
[1] Chifeng Univ, Dept Chem, Chifeng 024000, Neimenggu, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 04期
关键词：
crystal structure; thermal behaviors; supramolecule; Zn(II); COORDINATION POLYMERS; AMINO-ACIDS; COMPLEXES; NETWORKS;
D O I：
10.1080/15533174.2011.555869
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of two kinds of imidazole dicarboxylate ligands, 2-methyl-1H-imidazole-4,5-dicarboxylic acid (H3L1) or 2-ethyl-1H-imidazole-4,5-dicarboxylic acid (H3L2) with ZnSO4, or ZnCl2, resulted in two supramolecular complexes, namely [Zn(H2L1)2(H2O)2] (1) and {[Zn(H2L2)2(H2O)2]center dot 3H2O} (2). Molecular structures of the two complexes have been characterized by means of elemental analysis, IR, and single crystal X-ray diffraction. Their thermal behaviors have also been presented.
引用
收藏
页码：356 / 362
页数：7
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