Two Zinc(II) Supramolecules Constructed from Imidazole Dicarboxylate: Synthesis, Structures, and Properties

被引：2

作者：

Sang, Yali ^{[1
]}

Lin, Xuesong ^{[1
]}

Sun, Weidong ^{[1
]}

Yang, Suhua ^{[1
]}

机构：

[1] Chifeng Univ, Dept Chem, Chifeng 024000, Neimenggu, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 04期

关键词：

crystal structure; thermal behaviors; supramolecule; Zn(II); COORDINATION POLYMERS; AMINO-ACIDS; COMPLEXES; NETWORKS;

D O I：

10.1080/15533174.2011.555869

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of two kinds of imidazole dicarboxylate ligands, 2-methyl-1H-imidazole-4,5-dicarboxylic acid (H3L1) or 2-ethyl-1H-imidazole-4,5-dicarboxylic acid (H3L2) with ZnSO4, or ZnCl2, resulted in two supramolecular complexes, namely [Zn(H2L1)2(H2O)2] (1) and {[Zn(H2L2)2(H2O)2]center dot 3H2O} (2). Molecular structures of the two complexes have been characterized by means of elemental analysis, IR, and single crystal X-ray diffraction. Their thermal behaviors have also been presented.

引用

页码：356 / 362

页数：7

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