Use of natural binders and ionic liquid electrolytes for greener and safer lithium-ion batteries

被引：176

作者：

Kim, G. T. ^{[1
]}

Jeong, S. S. ^{[1
]}

Joost, M. ^{[1
]}

Rocca, E. ^{[1
]}

Winter, M. ^{[1
]}

Passerini, S. ^{[1
]}

Balducci, A. ^{[1
]}

机构：

[1] Univ Munster, Inst Phys Chem, D-48149 Munster, Germany

来源：

JOURNAL OF POWER SOURCES | 2011年 / 196卷 / 04期

关键词：

Lithium batteries; CMC; LiFePO4; Li4Ti5O12; Ionic liquid; PYR14FSI; ELECTROCHEMICAL PERFORMANCE; COMPOSITE ELECTRODES; POLYMER ELECTROLYTE; NEGATIVE ELECTRODE; LOW-COST; GRAPHITE; LIFEPO4; ANODES; WATER; CELLULOSE;

D O I：

10.1016/j.jpowsour.2010.09.080

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This manuscript reports on the development of a safe and green lithium-ion battery containing sodium salt of CarboxyMethylCellulose (CMC) as binder lithium tit mate (Li4Ti5O12) as anodic active material lithium iron phosphate (LiFePO4) as cathodic active material and an electrolytic solution based on the ionic liquid N-butyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide (PYR14FSI) The battery showed at room temperature a very stable specific capacity of 140 mAh g(-1) constant for more than 150 cycles This indicated that the introduction of low cost and environmentally benign binders like CMC and nonflammable electrolytes such as PYR14FSI represents a viable strategy for the development of new greener and safer lithium-ion batteries (C) 2010 Elsevier B V All rights reserved

引用

页码：2187 / 2194

页数：8

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