Use of natural binders and ionic liquid electrolytes for greener and safer lithium-ion batteries

被引:176
|
作者
Kim, G. T. [1 ]
Jeong, S. S. [1 ]
Joost, M. [1 ]
Rocca, E. [1 ]
Winter, M. [1 ]
Passerini, S. [1 ]
Balducci, A. [1 ]
机构
[1] Univ Munster, Inst Phys Chem, D-48149 Munster, Germany
关键词
Lithium batteries; CMC; LiFePO4; Li4Ti5O12; Ionic liquid; PYR14FSI; ELECTROCHEMICAL PERFORMANCE; COMPOSITE ELECTRODES; POLYMER ELECTROLYTE; NEGATIVE ELECTRODE; LOW-COST; GRAPHITE; LIFEPO4; ANODES; WATER; CELLULOSE;
D O I
10.1016/j.jpowsour.2010.09.080
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This manuscript reports on the development of a safe and green lithium-ion battery containing sodium salt of CarboxyMethylCellulose (CMC) as binder lithium tit mate (Li4Ti5O12) as anodic active material lithium iron phosphate (LiFePO4) as cathodic active material and an electrolytic solution based on the ionic liquid N-butyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide (PYR14FSI) The battery showed at room temperature a very stable specific capacity of 140 mAh g(-1) constant for more than 150 cycles This indicated that the introduction of low cost and environmentally benign binders like CMC and nonflammable electrolytes such as PYR14FSI represents a viable strategy for the development of new greener and safer lithium-ion batteries (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码:2187 / 2194
页数:8
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