Electrochemical processing and characterization of nickel hydroxide-polyelectrolyte films

被引：27
|
作者：
Zhitomirsky, I [1 ]
机构：
[1] McMaster Univ, Dept Mat Sci & Engn, Hamilton, ON L8S 4L7, Canada
来源：
MATERIALS LETTERS | 2004年 / 58卷 / 3-4期
关键词：
electrolytic deposition; electrophoretic deposition; nickel hydroxide; polyethylenimine; poly(diallyldimethylammonium chloride); film;
D O I：
10.1016/S0167-577X(03)00516-0
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Cathodic electrodeposition of composite materials based on nickel hydroxide and cationic polyelectrolytes was performed from NiCl2 solutions in ethanol-water solvent containing polyethylenimine and poly(diallyldimethylammonium chloride) (PDDA). The deposition mechanisms are based on electrolytic deposition of nickel hydroxide and electrophoretic deposition of the polyelectrolytes. The mechanisms of charging of polyelectrolyte macromolecules and the role of the solvent are discussed. The deposits were studied by X-ray diffraction and thermogravimetric analysis. The effect of heat treatment on the phase content of the deposits was analyzed. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：420 / 424
页数：5
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