Synthesis and structure of a stable cyclic dialkylgermylene

被引：63
|
作者：
Kira, M [1 ]
Ishida, S [1 ]
Iwamoto, T [1 ]
Ichinohe, M [1 ]
Kabuto, C [1 ]
Ignatovich, L [1 ]
Sakurai, H [1 ]
机构：
[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan
来源：
CHEMISTRY LETTERS | 1999年 / 03期
关键词：
D O I：
10.1246/cl.1999.263
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A stable cyclic dialkylgermylene(1) was synthesized by reductive dechlorination of the corresponding dichlorogermane (6) with sodium. Germylene 1 is monomeric both in solution and in the solid state, as observed by UV-vis spectroscopy and X-ray crystallography.
引用
收藏
页码：263 / 264
页数：2
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