Palladium(II) arenethiolates with chelating diamines: Formation of N-H center dot center dot center dot S hydrogen bonds with protonated N,N,N',N'-tetramethylethylenediamine

被引：17

作者：

Kapteijn, GM

Grove, DM

Smeets, WJJ

Kooijman, H

Spek, AL

vanKoten, G

机构：

[1] UNIV UTRECHT,DEBYE INST,DEPT MET MEDIATED SYNTH,3584 CH UTRECHT,NETHERLANDS

[2] UNIV UTRECHT,BIJVOET CTR BIOMOLEC RES,3584 CH UTRECHT,NETHERLANDS

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 02期

关键词：

D O I：

10.1021/ic950701a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of excess HSC6F5 with [Pd(OC6H5)(2)(R(2) NCH(2)CH(2)NR(2))] (R = Me, Et) affords either [Pd(SC6F5)(2)(Et(2)NCH(2)CH(2)NEt(2))] (1) or the unusual complex [Pd(SC6F5)(4)][Me(2)(H)NCH2CH2N(H)Me(2)] (2). The composition of the latter complex comprises a diprotonated tmeda ligand bridging over the metal center of a [Pd(SC6F5)(4)](2-) dianion in a unique way to form two intramolecular N-H ... S hydrogen bonds.

引用

页码：534 / &

页数：4

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