Bis(dicyclohexylammonium) μ-oxalato-κ4O1,O2:O1′,O2′-bis[aqua(oxalato-κ2O1,O2)diphenylstannate(IV)]

被引：11

作者：

Gueye, Ndongo ^{[1
]}

Diop, Libasse ^{[1
]}

Molloy, K. C. Kieran ^{[2
]}

Kociok-Koehn, Gabrielle ^{[2
]}

机构：

[1] Univ Cheikh Anta Diop, Lab Chim Minerale & Analyt, Dept Chim, Fac Sci & Tech, Dakar, Senegal

[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

X-RAY STRUCTURE; CRYSTAL-STRUCTURE; COMPLEXES;

D O I：

10.1107/S1600536810046738

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of the title compound, (C12H24N)(2)[Sn-2(C6H5)(4)( C2O4)(3)(H2O)(2)], consists of a bischelating oxalate ion, located on an inversion center, which is linked to two SnPh2 groups. The coordination sphere of the Sn(IV) ion is completed by a monochelating oxalate anion and a water molecule. The Sn(IV) atoms are thus seven-coordinated. The discrete binuclear units are further connected by hydrogen bonds, leading to a supramolecular crystal structure. The asymmetric unit contains one half dianion and one (Cy2NH2)(+) cation.

引用

页码：M1645 / U1464

页数：12

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